Products based on Ge and Si

ASTRAGERM-S (1-hydroxygermatrane monohydrate)

TS 2421-039-00209013-04

Application1-hydroxygermatran is used as a raw material for the manufacture of dietary supplement.

Parameters

Characteristics

Method

1

Appearance

White crystal powder

Industrial standard 20841.1-75

2

Color

White

Industrial standard 20841.1-75

3

Odor, taste

None

Industrial standard 20841.7-75

4

Mass fraction of Ge, %

Not less than 27

p. 6.3 of TS

5

Mass fraction of hydroxyl group, %

Not less than 10

Industrial standard 17537

Basic physical and chemical properties

Parameters

Characteristics

1

Solubility in water at 20оС

39%

2

Solubility in organic solvents

dimethylsulfoxide, dimethylformamide

3

Melting point

(198-199)оC

4

Oxygen ratio

It is not oxidized by air oxygen

Applications: Perfume and cosmetics industry, food industry, medicine, agriculture.

Examples of application: it is a component in biologically active additives "Astrogerm", "Aqua", "Germanorm" "longevity Balm", "Balm that restores vitality", "Biococtail" and perfumes and cosmetics "expansion of passion", "expansion of beauty", a series of creams for skin care of hands, feet, face and body.

- showed a positive effect when used as components of toothpastes.


Cherkaz (1-ethylsilane)

TS 2449-001-02068737-99

ApplicationPlant growth regulator

Parameters

Characteristics

Method

1

Appearance, color

White crystal powder

p. 4.1 of TS

2

Mass fraction of ethylsilatrane, %, not less than

96

p. 4.2 of TS

3

pH of 1% (by preparation) aqueous solution

6-8

p. 4.3 of TS

4

Mass fraction of water

0.5

p. 4.4 of TS

 Basic physical and chemical properties

Odor – None.

Solubility in water – well soluble in water (30%)

Melting point – 129-132 оС

Solubility in organic solvents – ethanol (20%), methanol (30%), dimethylsulfoxide (15%), toluene (12%).

ApplicationAgriculture, perfume and cosmetics industry

Application exapmles:

- successfully tested as a plant growth regulator in various regions of Russia (Moscow, Rostov, Samara region, Altai territory, etc.), as well as in the Shanghai region of China. The drug also showed positive results when used as a feed additive when feeding Pets (Samara region).

- tested and registered as components of cosmetics.

- showed a positive effect when used as components of toothpastes.


 

Bis(trichlorosilil)acetylene

Cl3SiC≡CSiCl3 Si2C2Cl6

Parameters

Characteristics

Method

1

Appearance, color

Transparent liquid from colorless to light yellow color

Industrial standard 20841.1-75

2

Odor

Strong smell (due to the release of hydrogen chloride)

Industrial standard 20841.1-75

3

The content of the basic substance,%, not less

97

Industrial standard 20841.1-75

Industrial standard 20841.8-79

Basic physical and chemical properties

Boiling point - 173-174°С

Melting temperature - 23-24°С

Upon contact with water, there is a rapid reaction of hydrolysis of Si-Cl bonds, accompanied by the release of hydrogen chloride.

Application: It is used for the synthesis of silyl-containing norbornadienes-monomers to produce high-performance gas separation membranes.

It can be used as a modifier of Organoelement oligomers and polymers (for the introduction of unsaturated fragments into the structure).

 Application examples:

  • new silyl-containing norbornadienes have been obtained at the Topchiev Institute of Economics of the Russian Academy of Sciences on the basis of bistrichlorosilyl acetylene, which are of interest both in terms of scientific study and in the applied aspect.

 

β,β- Dichlorophenyltrichlorosilane

Cl3SiCH=CCl2 Si1C2H1Cl5

Parameters

Characteristics

Method

1

Appearance, color

Transparent liquid from colorless to light yellow

Industrial standard 20841.1-75

2

Odor

Strong smell (due to the release of hydrogen chloride)

Industrial standard 20841.1-75

3

The content of base material %, not less than

97

Industrial standard 20841.7-75

Industrial standard 20841.8-79

Basic physical and chemical properties

Boiling point - 162-163°С

Reflective index (nD20) - 1,4945

Density (d420) - 1,5523

Upon contact with water, there is a rapid reaction of hydrolysis of Si-Cl bonds, accompanied by the release of hydrogen chloride.

Application: It is used to produce high-performance fast-acting crosslinking agents of silicone rubbers with terminal hydroxyl groups.

It can be used as a modifier of Organoelement oligomers and polymers (for the introduction of siloxane links with dichlorvinyl groups into the structure). 

Application examples:

- at the pilot plant of GNIIChTEOS the technology for obtaining the product 103-310 has been worked out (a mixture of β,β-dichlorvinyltrichlorosilane and bistrichlorosilyl acetylene), and based on it, a new cross linking high-performance cross linking agent-product 103-311 (a mixture of β,β-dichlorvinyltrisacetoxymoxylane and bis(trisacetoxymoxylyl)acetylene's), β-chlorovinyldichloroarsine. When using this product, the vulcanization rate (compared to traditional vinyltrisacetoxymooxylane) increases by more than 10 times. 


 

Perchlorvinyltrichlorosilane

Cl3SiCCl≡CCl2 Si1C2Cl6

Parameters

Characteristics

Method

1

Appearance, color

Transparent liquid from colorless to light yellow

Industrial standard 20841.1-75

2

Odor

Strong smell (due to the release of hydrogen chloride)

Industrial standard 20841.1-75

3

The content of base material %, not less than

97

Industrial standard 20841.7-75

Industrial standard 20841.8-79

 

Basic physical and chemical properties

Boiling point - 189-191°С

Reflective index (nD20) - 1,5186

Density (d420) - 1,6766

Upon contact with water, there is a rapid reaction of hydrolysis of Si-Cl bonds, accompanied by the release of hydrogen chloride.

Applications: It can be used to produce a double-acting photoresist material. It can be used as a modifier of Organoelement oligomers and polymers (for the introduction of siloxane links with perchlorvinyl groups into the structure).

Application examples

- in laboratory conditions, solid, soluble, stable during storage silsesquioxanes (Cl2C=CClSiO1.5)n were obtained, suitable for use as a photoresist material of positive or negative type, depending on the technology of forming a resistive image.


 

Phenyltrichlorgermanium

C6H5GeCl3 GeC6H5Cl3

Parameters

Characteristics

Method

1

Appearance, color

Transparent liquid from colorless to light yellow

Industrial standard 20841.1-75

2

Odor

Strong smell (due to the release of hydrogen chloride)

Industrial standard 20841.1-75

3

The content of base material %, not less than

97

Industrial standard 20841.7-75

Industrial standard 20841.8-79

Basic physical and chemical properties

Boiling point - 118-119°С//24 mm. Hg

Refractive index (яD20) - 1.5540

Density (d420) - 1.5972

Upon contact with water, there is an intensive hydrolysis reaction of Ge-Cl bonds, accompanied by the release of hydrogen chloride.

Application:

- It is possible to use as a modifier of Organoelement oligomers and polymers (for the introduction of phenylhermoxane links into the structure).

- For the synthesis of biologically active compounds.


 

Diphenyldichlorgermanium

(C6H5)2GeCl2 Ge1C12H10Cl2

 

Parameters

Characteristics

Method

1

Appearance, color

Transparent liquid from colorless to light yellow

Industrial standard 20841.1-75

2

Odor

Strong smell (due to the release of hydrogen chloride)

Industrial standard 20841.1-75

3

The content of base material %, not less than

97

Industrial standard 20841.7-75

Industrial standard 20841.8-79

Basic physical and chemical properties

Boiling point - 223°С//12 mm. Hg

Refractive index (яD20) - 1,5975

Upon contact with water, there is an intensive hydrolysis reaction of Ge-Cl bonds, accompanied by the release of hydrogen chloride.

Application:

- It is possible to use as a modifier of Organoelement oligomers and polymers (for the introduction of phenylhermoxane links into the structure).

- For the synthesis of biologically active compounds.

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